Your bishop or stake RS leaders would be good people to ask that question. Until someone who knows the real answer replies, there is language in Handbook 2 (publicly viewable) that appears to shed some light on the question. In section 9.5.2, bullet point 1, second sentence, it says this: "The Relief Society presidency recommends ministering companionships and ministering assignments for Relief Society sisters." At least in earlier years, YW were not considered "Relief Society sisters."